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Improvement in Optical Properties of Nuclear Track Detector

机译:核径迹探测器光学特性的改进

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The purpose of this work was obtaining information about the interaction of γ- ray with CR-39 track detector by using the UV-Vis spectrometry and FTIR which can be used in concerning sensor for gamma irradiation. CR-39 samples irradiated by radioactive source Co-60 at different doses are (0, 100, 200, 300, 400, and 500 kGy). The UV-Vis spectroscopy show transitions electronic in the visible region from ground state to excited state, by increasing gamma doses, and the absorbance spectrum for all samples take the same behavior with slightly shift. This shift due to decrease in the optical band gap energy E_g. The FTIR spectra show for all samples there are increases in the intensity of the characteristic peaks with increasing gamma ray, at 3234, 2367 and 1817 cm~(-1), this increase may be related to more oxidation process that, in turn was produced on the polymer chains by increase gamma doses, and the number of peaks at 1817, 2367, 2645 and 3234 cm~(-1) is belong to carbonate group C=O stretching vibration, O=C=O asymmetric by stretching, C-H Stretching, H_2O free stretching vibration, respectively. By increase gamma ray did not observed changes in the CR-39 groups but observed change in the intensities of peaks, then CR-39 detector can be used properly in the field of radiation dosimetery.
机译:这项工作的目的是通过使用UV-Vis光谱仪和FTIR获得有关γ射线与CR-39轨道探测器的相互作用的信息,这些信息可用于有关伽马辐射的传感器。放射源Co-60以不同剂量照射的CR-39样品为(0、100、200、300、400和500 kGy)。 UV-Vis光谱显示,通过增加γ剂量,可见光区域中的电子从基态跃迁到激发态,所有样品的吸收光谱都表现出相同的行为,但有轻微的偏移。该偏移是由于光学带隙能量E_g的减小而引起的。 FTIR光谱表明,在3234、2367和1817 cm〜(-1)处,所有样品的特征峰强度都随γ射线的增加而增加,这种增加可能与更多的氧化过程有关,反过来又产生了γ剂量增加,在聚合物链上出现峰,在1817、2367、2645和3234 cm〜(-1)处的峰数属于碳酸盐基团C = O拉伸振动,O = C = O通过拉伸不​​对称,CH拉伸,H_2O自由拉伸振动。通过增加伽马射线,未观察到CR-39组的变化,但是观察到峰强度的变化,则CR-39检测器可在辐射剂量计领域中正确使用。

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