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Efecto de la difusión de ión cloruro en el comportamiento de acero galvanizado en estructuras de hormigón armado: Resultados preliminares

机译:氯离子扩散对钢筋混凝土结构中镀锌钢性能的影响:初步结果

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Galvanized steel behavior in concretes of different types of cement is very important for new mega construction projects with requirements of durability in highly aggressive environments such as sea water, in harbor structures as in mining projects that use sea water in their processes. To emulate conditions of this type of project, it was used W/C ratio 0.45. Measurements of mechanical and physical properties of concretes based on Pure Portland cement and Pozzolanic Portland cement were made: compressive strength, capillary absorption, total porosity and capillary absorption coefficient, resistance to water penetration, capillary absorption and effective porosity were calculated. The specimens made with ordinary steel and galvanized steel were subjected to drying semi-immersion cycles in 2.56 M sodium chloride solution, and measurements of corrosion potential, polarization resistance, corrosion current, analysis of chlorides and pH were made periodically. The results justify the conclusion that regardless of type of cement used in concretes investigated, galvanized steel shows passivity to 19 drying semi-immersion, and ordinary steel is active from cycle 16. After the cycle 19 galvanized steel 19 in concrete made with pozzolanic Portland cement begins to show activity in a saline environment. However, the high salt conditions are not yet enough to activate the galvanized steel in concrete with ordinary Portland cement.
机译:对于要求在腐蚀性强的环境(例如海水),港口结构以及在其过程中使用海水的采矿项目中具有耐久性要求的新型大型建筑项目,在不同类型的水泥混凝土中镀锌的钢性能非常重要。为了模拟此类项目的条件,使用了W / C比0.45。测量了基于纯硅酸盐水泥和火山灰硅酸盐水泥的混凝土的机械和物理性能:计算了抗压强度,毛细吸收,总孔隙率和毛细吸收系数,耐水渗透性,毛细吸收和有效孔隙率。用普通钢和镀锌钢制成的试样在2.56 M氯化钠溶液中进行干燥半浸没循环,并定期进行腐蚀电位,耐极化性,腐蚀电流,氯化物和pH分析的测量。结果证明了以下结论:无论所研究的混凝土中所用的水泥类型如何,镀锌钢均表现出对19干半浸的钝化性,而普通钢从循环16开始就具有活性。在循环19之后,用火山灰硅酸盐水泥制成的混凝土中的镀锌钢19表现出活性。开始在盐环境中显示活动。然而,高盐条件还不足以活化普通硅酸盐水泥中的镀锌钢。

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