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首页> 外文期刊>Results in Physics >Yttrium doped TiO2 porous film photoanode for dye-sensitized solar cells with enhanced photovoltaic performance
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Yttrium doped TiO2 porous film photoanode for dye-sensitized solar cells with enhanced photovoltaic performance

机译:钇掺杂的TiO 2 多孔膜光阳极,用于染料敏化太阳能电池,具有增强的光伏性能

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Highlights ? Yttrium doped TiO 2 nanocrystal photoanodes were fabricated by a hydrothermal method. ? Improved electron transfer kinetics were found for the yttrium doped cell. ? The efficiency of DSSC improved by 27.9% compared with pristine DSSC. Abstract In this paper, TiO 2 photoanodes were doped with yttrium under different doping concentrations via hydrothermal method and further employed to assemble dye-sensitized solar cells (DSSCs). XRD, XPS, SEM, TEM, UV–Vis DRS and PL measurements were carried out to investigate the yttrium doping effects on crystal structure, chemical status, optical properties and dye loading capacity of the photoanodes. The photovoltaic performance of the photoanodes with various yttrium doping concentration was measured by recording the photocurrent-photovoltaic curves, and the result indicated that TiO 2 :0.006 Y exhibited the best power conversion efficiency with high short circuit current density (J sc ) and open circuit voltage (V oc ). This improvement may be due to the enhanced visible light harvesting, increased dye loading capacity and reduced photoelectron recombination.
机译:强调 ?采用水热法制备了掺钇的TiO 2纳米晶体光阳极。 ?发现钇掺杂电池的电子转移动力学得到改善。 ?与原始DSSC相比,DSSC的效率提高了27.9%。摘要本文采用水热法在不同掺杂浓度下将钇掺杂在TiO 2光阳极上,并进一步用于组装染料敏化太阳能电池。进行了XRD,XPS,SEM,TEM,UV-Vis DRS和PL测量,以研究钇掺杂对光阳极的晶体结构,化学状态,光学性质和染料负载量的影响。通过记录光电流-光伏曲线,测量了不同钇掺杂浓度的光阳极的光伏性能,结果表明:TiO 2:0.006 Y表现出最佳的功率转换效率,且短路电流密度(J sc)高,开路电压(V oc)。这种改善可能是由于增强了可见光的收集,增加了染料的负载量以及减少了光电子的重组。

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