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Preparation and UV Characterization of TiO2 Nanoparticles Synthesized by Sanss

机译:Sanss合成的TiO 2 纳米粒子的制备及紫外表征

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This paper proposes preparation and investigation of UV characterization of TiO2 nanocomposite synthesized by SANSS. A Submerge Arc Nano particles Synthesis System (SANSS) to produce TiO2 nano particles in deionized water without any of dispersant [1,2] has been successfully accomplished in this study. Uniform dispersion, deep UV optical absorption, and crystalline structure of TiO2 nano particles are investigated. Particularly, deep UV absorbance is the unique characteristic of TiO2 nano particles synthesized by SANSS. The evidence of deep UV absorbance reveals the unique quantum effect of TiO2 nano particles suspend in deionized water. As a result, the observed absorbance pattern indicates absorbent energy of TiO2 nano fluids synthesized by proposed method is higher than that of TiO2 nano fluids prepared by other conventional fabrication process. The observed UV absorbance of the nano fluids demonstrates the TiO2 molecular tends to react with higher activation energy. After being exposed to the UV light irradiation, the TiO2 nano particles will spontaneously correspond for photo catalytic reaction mechanism through hydroxyl radicals with higher kinetic energy which can cause decomposition of high energetic covalent bond such as C=C, C-H, etc (Legan , 1982) [3]. The result of the experiment indicates that VOC (volatile organic compounds) with C-C, C=C, C-H structures such as Toluene now is more effectively to be decomposed by UV irradiation with existence of TiO2 nano particles synthesized by proposed SANSS process.
机译:本文提出并研究了SANSS合成的TiO 2 纳米复合材料的紫外特性。这项研究成功地完成了在去离子水中制备TiO 2 纳米颗粒而无分散剂[1,2]的潜弧纳米颗粒合成系统(SANSS)。研究了TiO 2 纳米粒子的均匀分散,深紫外吸收和晶体结构。特别是,深紫外吸收是SANSS合成的TiO 2 纳米粒子的独特特征。深紫外线吸收的证据揭示了TiO 2 纳米颗粒悬浮在去离子水中的独特量子效应。结果,观察到的吸光度图表明通过所提出的方法合成的TiO 2 纳米流体的吸收能高于通过其他常规制造工艺制备的TiO 2 纳米流体。观察到的纳米流体的紫外吸收表明,TiO 2 分子倾向于与更高的活化能发生反应。 TiO 2 纳米粒子在暴露于紫外光照射后,会通过具有较高动能的羟基自由基自发地参与光催化反应机理,这会引起高能共价键(如C = C)的分解,CH等(Legan,1982)[3]。实验结果表明,具有合成的TiO 2 纳米粒子的存在下,UV,UV能更有效地分解具有CC,C = C,CH结构的VOC(挥发性有机化合物),如甲苯。通过提议的SANSS流程。

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