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Fabrication of TiO2 Nanosheet Aarrays/Graphene/Cu2O Composite Structure for Enhanced Photocatalytic Activities

机译:TiO 2 纳米片/石墨烯/ Cu 2 O复合结构的制备及其光催化活性

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TiO~(2) NSAs/graphene/Cu~(2)O was fabricated on the carbon fiber to use as photocastalysts by coating Cu~(2)O on the graphene (G) decorated TiO~(2) nanosheet arrays (NSAs). The research focus on constructing the composite structure and investigating the reason to enhance the photocatalytic ability. The morphological, structural, and photocatalytic properties of the as-synthesized products were characterized. The experimental results indicate that the better photocatalytic performance is ascribed to the following reasons. First, the TiO~(2) NSAs/graphene/Cu~(2)O composite structure fabricated on the carbon cloth can form a 3D structure which can provide a higher specific surface area and enhance the light absorption. Second, the graphene as an electron sink can accept the photoelectrons from the photoexcited Cu~(2)O which will reduce the recombination. Third, the TiO~(2) nanosheet can provide more favorable carrier transportation channel which can reduce the recombination of carriers. Finally, the Cu~(2)O can extend the light absorption range.
机译:通过在石墨烯(G)装饰的TiO〜(2)纳米片阵列(NSA)上涂覆Cu〜(2)O,在碳纤维上制备了TiO〜(2)NSAs /石墨烯/ Cu〜(2)O用作光致催化剂。 。研究的重点是构建复合结构并研究提高光催化能力的原因。表征了合成产物的形态,结构和光催化性能。实验结果表明,较好的光催化性能归因于以下原因。首先,在碳布上制造的TiO〜(2)NSAs /石墨烯/ Cu〜(2)O复合结构可以形成3D结构,可以提供更高的比表面积并增强光吸收。其次,作为电子吸收体的石墨烯可以接受来自光激发的Cu〜(2)O的光电子,这将减少复合。第三,TiO〜(2)纳米片可以提供更有利的载流子传输通道,从而减少载流子的复合。最后,Cu〜(2)O可以扩展光吸收范围。

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