Recycling Y and Eu from Waste Fluorescent Powder and High Temperature Solid-State Synthesis of Y 2 O 3 :Eu Phosphors

摘要

Y 2 O 3 :Eu were prepared through precursors synthesized by leaching tests, removing impurities, enrichment of Y and Eu from residual purified liquors, annealing treatment, and high temperature solid-state reaction method, which is the most suitable for large-scale production. The analysis of product shows that the purity is 99.42%. The resultant powders were characterized by X-ray diffraction (XRD), differential thermal analysis (TG-DTA), scanning electron microscope (SEM), and photoluminescence (PL). Compared with the commercial phosphors, the XRD spectrum of the product samples revealed the synthesized particles to have a pure cubic Y 2 O 3 :Eu structure without any impurities in the crystalline phase. On the morphology, the Y 2 O 3 :Eu particles synthesized by a combustion and high temperature solid state process with sintering aids, were large and uniform. For luminescence property, the emission intensity of Y 2 O 3 :Eu phosphors synthesized by combustion process and high temperature solid state process with sintering aids were higher than those without sintering aids, at 1400 ???°C.