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Membrane Formation in Liquids by Adding an Antagonistic Salt

机译:通过添加拮抗盐在液体中形成膜

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Antagonistic salts are composed of hydrophilic and hydrophobic ions. In a binary mixture, such as water and organic solvent, these ion pairs preferentially dissolve to those phases, respectively, and there is a coupling between the charge density and the composition. The heterogeneous distribution of ions forms a large electric double layer at the interface between these solvents. This reduces the interfacial tension between water and organic solvent, and stabilizes an ordered structure, such as a membrane. These phenomena have been extensively studied from both theoretical and experimental point of view. In addition, the numerical simulations can reproduce such ordered structures.
机译:拮抗盐由亲水和疏水离子组成。在二元混合物(例如水和有机溶剂)中,这些离子对分别优先溶解在这些相中,并且电荷密度和组成之间存在耦合。离子的异质分布在这些溶剂之间的界面处形成一个大的双电层。这降低了水和有机溶剂之间的界面张力,并稳定了有序结构,例如膜。这些现象已经从理论和实验的角度进行了广泛的研究。另外,数值模拟可以再现这种有序结构。

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