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Predicting the Dielectric Response of Saturated Sandstones Using a 2-electrode Measuring System

机译:使用两电极测量系统预测饱和砂岩的介电响应

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4-electrode setups are usually used to measure the dielectric response (complex conductivity)of sandstones, as it is known that 2-electrode systems are sensitive to unwantedelectrode polarization at low frequency. Moreover, electrode polarization (EP) occurs inthe frequency range where the characteristic relaxation associated to the grain size also occurs, which can therefore theoretically be assessed using 4-electrode setups. Nonetheless, we find that other parameters of interest (porosity, salinity) can easily be extracted from the frequency range 1 - 10 kHz, beyond the one affected by EP using a 2 electrode setup. An additional unwanted effect (a??pseudo-inductancea??) is observed in the frequency range 10 kHz - 1 MHz during our experiments. Even though the origin of this effect remains unknown, it is shown to be correlated with the ionic strength of the system and the electrode separation. The bulk polarization region, i.e. the region of intermediate frequencies devoid of EP and pseudo-inductance polarizations, is the one of interest, as the complex conductivity of the system is there only dependent on material parameters such as the porosity of the sandstone and the conductivity of the electrolyte. We demonstrate that in the bulk region the model predicts the complex conductivity response, when these porosity and ionic strength are known. The model has been validated using laboratory measurements on a Bentheim sandstone saturated with five different NaCl concentrations: 5 mM, 10 mM, 100 mM, 170 mM and 540 mM.
机译:四电极设置通常用于测量砂岩的介电响应(复电导率),因为众所周知,两电极系统对低频下的有害电极极化敏感。此外,电极极化(EP)发生在与晶粒尺寸相关的特征弛豫也发生的频率范围内,因此理论上可以使用4电极设置进行评估。尽管如此,我们发现,使用2电极设置,可以很容易地从1-10 kHz的频率范围中提取其他感兴趣的参数(孔隙度,盐度),而不受EP影响的参数。在我们的实验中,在10 kHz-1 MHz的频率范围内观察到了另一种不想要的效应(αε假电感aε)。即使这种作用的起因仍是未知的,也显示与系统的离子强度和电极间距有关。体极化区域,即没有EP和伪电感极化的中频区域,是感兴趣的区域之一,因为系统的复电导率仅取决于材料参数,例如砂岩的孔隙度和电导率电解质。我们证明,在这些孔隙率和离子强度已知的情况下,该模型可以预测大部分区域的电导率响应。该模型已使用在五种NaCl浓度饱和的Bentheim砂岩上的实验室测量值进行了验证:5 mM,10 mM,100 mM,170 mM和540 mM。

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