Estimation of Effective Diffusion Coefficient of O 2 in Ash Layer in Underground Coal Gasification by Thermogravimetric Apparatus

摘要

Underground coal gasification (UCG) proceeds generally in the presence of an ash layer on coal (or char) surface. The ash layer increases the mass transfer resistance of O 2 to the gasification surface, which may become the limiting step of whole process. This paper studies O 2 diffusion in ash layer formed on cylindrical char samples using a specially designed one-dimension setup in a thermogravimetric apparatus (TGA). The effective internal diffusion coefficient ( D e ) is found to increase with an increase in ash layer thickness, due to an increase in median pore diameter. Methods are established to correlate D e with operating conditions and to estimate the role of internal diffusion resistance in overall mass transfer resistance.