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Comment on “Next‐Generation Ice Core Technology Reveals True Minimum Natural Levels of Lead (Pb) in the Atmosphere: Insights From the Black Death” by More et al.

机译:More等人的评论“下一代冰芯技术揭示了大气中真正的最低自然铅(Pb):黑死病的见解”。

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Over the past four decades numerous studies of lake sediment, marine sediment, and peat from sites in close proximity to mining or metallurgical centers and in remote locations have detailed local and regional histories of lead (Pb) pollution in Europe. Contrary to More et al.'s (2017, https://doi.org/10.1002/2017GH000064) claim that “previous assumptions about preindustrial “natural” background lead levels in the atmosphere have been misleading,” these studies have clearly shown that true natural background conditions occurred more than 2,500 or even 3,500 years ago, and Pb pollution has proceeded uninterrupted since. The implications of this have been discussed within the context of environmental policy, for example, European Water Framework Directive. Though these records reflect a common European narrative of mining, metallurgy, and pollution, each reflects a combination of local and regional events, leading to differences in the timing and intensity of changes in each Pb record. No one record—ice or otherwise—fully represents the three millennia Pb pollution history in Europe. While the resolution of the ice record is impressive, there are questions about its interpretation. First, the authors discount local and regional Pb sources, whereas there is a close connection between the mining history in an area 40 km from the glacier and changes in a nearby lake Pb record; second, significant changes in ice chemistry cooccurring with the lowest Pb values are overlooked. A sharp increase in Ca/Fe ratios occurs precisely with the steepest Pb declines during the Black Death and mid‐1400s, suggesting additional processes influencing the Pb record.
机译:在过去的四十年中,在靠近采矿或冶金中心以及偏远地区的许多地点对湖泊沉积物,海洋沉积物和泥炭进行了许多研究,详细记录了欧洲当地和区域铅(Pb)污染的历史。与More等人(2017,https://doi.org/10.1002/2017GH000064)相反,他们声称“关于大气中工业化前“自然”背景铅水平的先前假设具有误导性,”这些研究清楚地表明:真正的自然本底条件发生在2500年前,甚至3500年前,并且自那时以来,Pb的污染一直没有间断。已经在环境政策的背景下(例如,《欧洲水框架指令》)讨论了这一点的含义。尽管这些记录反映了欧洲对采矿,冶金和污染的共同描述,但每个记录都反映了本地和区域性事件的组合,从而导致每个Pb记录变化的时间和强度的差异。没有任何记录(无论是冰还是其他记录)完全代表了欧洲三千年的铅污染历史。尽管冰记录的分辨率令人印象深刻,但对其解释存在疑问。首先,作者不考虑本地和区域铅的来源,而距冰川40公里的区域的采矿历史与附近铅湖记录的变化之间存在密切的联系。其次,忽略了伴随最低的Pb值发生的冰化学变化。钙/铁比的急剧增加恰恰发生在黑死病和1400年代中期,铅的下降幅度最大,这表明影响铅记录的其他过程。

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