Mineral chemistry and isotope geochemistry of pyrite from the Heilangou gold deposit, Jiaodong Peninsula, Eastern China

摘要

The Heilangou gold deposit is located in the northern Qixia–Penglai gold belt, which is one amongst the three large gold belts in the eastern Shandong Province (Jiaodong Peninsula). The ore body has formed within the Guojialing granite. In this study, we report the mineral chemistry of pyrite, as well as the S, Pb, and H–O isotope data of the Heilangou gold deposit. The chemical composition of pyrite in the Heilangou gold deposit indicates that the associated gold deposit is a typical magmatic hydrothermal one. The geochemical signatures and crystal structure of pyrite show that the ore-forming materials have been derived from the crust. The S isotope data of the pyrites from Heilangou show an overall range from 5.5 to 7.8‰ and an average of 6.7‰. The S isotope data in this deposit are similar to those from the deposits in the Jiaodong gold belt. The Pb and S isotope variations are small in the Heilangou gold deposit. The 206 Pb/ 204 Pb, 207 Pb/ 204 Pb and 208 Pb/ 204 Pb ratios are 17.4653–17.5958, 15.5105–15.5746 and 38.0749–38.4361, respectively. These data plot between the lower crust and the orogenic belt. The Pb isotope data in the Heilangou gold deposit are similar to those in the Linglong gold deposit. From the Qixia gold area (the Liukou and Majiayao gold deposits) to the Muping–Rushan gold belt (Rushan gold deposit) to the Zhao–Ye gold belt (the Linglong, Sanshandao and Jiaojia gold deposits), the 206 Pb/ 204 Pb ratios progressively increase. The D–O isotope data obtained from quartz separates suggest that the ore-forming fluid was similar to a mixture of magmatic and meteoric waters. These results suggest that the ore-forming elements were primarily from source fluids derived from the lower crust. Graphical abstract Display Omitted Highlights ? Characteristics of Mesozoic gold deposit. ? S, Pb, H and O isotopes reveal magmatic–hydrothermal history. ? Geochemistry suggests crustal source for gold.