Soft template synthesis of aza- and thiazametalmacrocyclic compounds in thin gelatin films

摘要

The problems concerned with the processes of template synthesis of 3 d -element aza- and thiazametalmacrocyclic complexes that happen in nano reactors on the basis of thin films metalhexacya-noferrate(II) gelatin-immobilized matrix implants under their contact with water solutions containing various (N,O,S)-donor atomic ligands and organic compounds having one or two carbonyl groups have been considered. It was noted that, in a series of cases, the variety of metalmacrocyclic compounds obtained at template synthesis in such specific conditions considerably differs from that of metalmacrocycles formed at the conditions traditional for chemical synthesis.