首页> 外文期刊>International Journal of Mining and Geo-Engineering >Kinetics of chalcopyrite galvanic leaching using sulfate media at the low temperature in the GalvanoxTM process
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Kinetics of chalcopyrite galvanic leaching using sulfate media at the low temperature in the GalvanoxTM process

机译:GalvanoxTM工艺中在低温下使用硫酸盐介质浸出黄铜矿的电动力学

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In this research work, the dissolution of chalcopyrite was investigated under atmospheric pressure, with sulfate media at low temperatures, in 30°C to 50°C. In the galvanic interaction between chalcopyrite and pyrite, pyrite is used as a leaching catalyst. Effects of different parameters such as temperature, stirring speed, pyrite to chalcopyrite ratio, particle size, and solution potential were examined. Results showed that maximum copper recovery in low temperature was achieved after 24 hours, under the following condition: stirring speed of 800 rpm, pyrite to chalcopyrite ratio 4, solution potential 440 mV, temperature 50°C, and particle size of -38 microns. In addition, kinetic studies indicated that chalcopyrite dissolution with pyrite followed the shrinking core model, and the reaction was controlled by the surface reaction. Activation energy (Ea) was calculated as 88 kJ/mol.
机译:在这项研究工作中,在大气压下,在30°C至50°C的低温下,用硫酸盐介质研究了黄铜矿的溶解。在黄铜矿与黄铁矿之间的电流相互作用中,黄铁矿用作浸出催化剂。检查了不同参数的影响,例如温度,搅拌速度,黄铁矿与黄铜矿的比率,粒度和溶液电位。结果表明,在以下条件下,经过24小时后,在低温下可获得最大的铜回收率:搅拌速度为800 rpm,黄铁矿与黄铜矿的比率为4,溶液电势为440 mV,温度为50°C,粒径为-38微米。另外,动力学研究表明,黄铁矿在硫铁矿中的溶解遵循收缩核模型,且反应受表面反应控制。活化能(Ea)经计算为88kJ / mol。

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