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UV Irradiation Chlorine Dioxide Photocatalytic Oxidation of Simulated Fuchsine Wastewater by UV-Vis and Online FTIR Spectrophotometric Method

机译:紫外-可见和在线FTIR分光光度法对模拟品红废水进行紫外线辐射二氧化氯光催化氧化

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The photocatalyst TiO2/SiO2was prepared and used for chlorine dioxide photocatalytic oxidation of simulated fuchsine wastewater under UV irradiation. The removal efficiency of fuchsine treated by photocatalytic oxidation process is higher than that of chemical oxidation process. By using UV-Vis and online FTIR analysis technique, the intermediates during the degradation process were obtained. The benzene ring in fuchsine was degraded into quinone and carboxylic acid and finally changed into carbon dioxide and water during the photocatalytic oxidation. The degradation reaction mechanism of fuchsine by UV irradiation chlorine dioxide photocatalytic oxidation was proposed based upon the experiment evidence.
机译:制备了光催化剂TiO2 / SiO2并将其用于紫外光照射下模拟品红废水的二氧化氯光催化氧化。光催化氧化法处理品红的去除率高于化学氧化法。利用紫外可见光谱和在线FTIR分析技术,获得了降解过程中的中间体。品红中的苯环在光催化氧化过程中被降解为醌和羧酸,最后变为二氧化碳和水。基于实验证据,提出了紫红色素在紫外线照射下二氧化氯光催化氧化降解反应的机理。

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