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The Conceptual Meaning of ThermodynamicEntropy in the 21st Century1

机译:21世纪热力学熵的概念意义1

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Although entropy change – the process described by Clausius and characterized as the second law of thermodynamics – involves only two terms, energy change and temperature, neither he nor distinguished scientists of the past century focused on that fact. The novel word “entropy” apparently drew them to concentrate on its ‘meaning’ rather than on dq, the energy becoming spread out or dispersed in phase space in any spontaneous process. Today, beginners and experts can readily see that process as fundamental in thermodynamic change.
机译:尽管熵变化(由克劳修斯(Clausius)描述并被称为热力学第二定律的过程)仅涉及两个术语,即能量变化和温度,但他和上个世纪的杰出科学家都没有关注这一事实。新颖的“熵”一词显然吸引他们将注意力集中在其“含义”上,而不是在dq上,能量在任何自发过程中都散布或分散在相空间中。如今,初学者和专家都可以轻松地将该过程视为热力学变化的基础。

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