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Rheological Behaviors of Bio-degradable Drilling Fluids in Horizontal Drilling of Unconsolidated Coal Seams

机译:非固结煤层水平钻井中可生物降解钻井液的流变行为

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In China, horizontal drilling techniques have been widely used in the exploration of coalbed methane (CBM). The drill-in fluids, especially in unconsolidated coal seams, are typically comprised of cellulose polymers, xanthan polymers and guar gums. However, testing and experience have shown that insufficient degradation of filter cakes resulting from even this “clean” drill-in fluids can significantly impede flow capacity at the wellbore wall. Past approaches to minimizing the damage have been the application of strong acids or oxidative breakers systems. They are often only marginally successful, particularly when applied in extended length intervals. Therefore, this paper introduced an engineered technique incorporating non-toxic, environment friendly and economically attractive bio-degradable drilling fluids (BDF). Extensive lab tests were conducted to evaluate the effects of substrate (polymer) type, substrate concentration, enzyme type and enzyme concentration on the viscosity breaking behaviors of BDFs. We got the conclusions as follows. (1) Power Law model was the best model to matching the rheological properties of BDFs; (2) Compared with konjak, the degradations of Na-CMC and guar gum were easier to be controlled; (3) In the degradation of CMC by enzyme SE-1, the optimal weight concentration ratio of CMC to SE-1 was 3 to 1; (4) Of the three enzymes, enzyme SE-2 had the highest activity and could be used to degrade polymer in shorter time; (5) Higher enzyme concentration could speed up the degradation reaction; (6) Viscosity breaking times fluctuating from 13.5 hours to 74.5 hours and viscosity breaking ratios varying from 20% to 100% could be achieved by modifying the formulations of BDFs.
机译:在中国,水平钻探技术已广泛用于煤层气(CBM)的勘探。钻井液,特别是在非固结煤层中,通常由纤维素聚合物,黄原胶聚合物和瓜尔豆胶组成。但是,测试和经验表明,即使是这种“干净”的钻井液,也会导致滤饼的降解不充分,从而严重阻碍井眼壁的流量。过去将损害最小化的方法是强酸或氧化性破胶剂体系的应用。它们通常仅取得少许成功,尤其是在延长的时间间隔内应用时。因此,本文介绍了一种工程技术,该技术结合了无毒,环境友好和经济上有吸引力的生物可降解钻井液(BDF)。进行了广泛的实验室测试,以评估底物(聚合物)类型,底物浓度,酶类型和酶浓度对BDF粘度破坏行为的影响。我们得出以下结论。 (1)幂律模型是匹配BDF流变特性的最佳模型; (2)与魔芋相比,Na-CMC和瓜尔胶的降解更容易控制; (3)SE-1酶降解CMC时,CMC与SE-1的最佳重量浓度比为3∶1。 (4)三种酶中,SE-2酶的活性最高,可在较短的时间内降解聚合物。 (5)较高的酶浓度可加快降解反应; (6)通过改变BDF的配方,可以实现13.5小时至74.5小时的粘度破坏时间,并且粘度破坏率可以在20%至100%之间变化。

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