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Effects of Graphite on the Corrosion Behavior of Aluminum-Graphite Composite in Sodium Chloride Solutions

机译:石墨对铝碳复合材料在氯化钠溶液中腐蚀行为的影响

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A series of different aluminum-graphite composites (Al-Gr), namely pure Al, Al-1%Gr, Al-2%Gr, andAl-3%Gr, was fabricated. The surface of these composites was investigated using optical microscopyto examine the distribution of exfoliated graphite within aluminum. The corrosion behavior of the pureAl and Al-Gr composites after different immersion intervals in 3.5% NaCl solutions was carried outusing cyclic potentiodynamic polarization (CPP), chronoamperometry (CA), and electrochemicalimpedance spectroscopy (EIS). The study was also complimented by scanning electron microscopy(SEM) and energy dispersive X-ray (EDX) investigation. Corrosion measurements indicated that thepresence of Gr and the increase of its content raise the corrosion rate and reduce the polarizationresistance of Al. Increasing the immersion time of the test samples in the chloride solutions beforemeasurements was found to decrease the general corrosion and increase the pitting corrosion.SEM/EDX investigations revealed that the presence of Gr activates the corrosion of Al due to theoccurrence of galvanic corrosion and this effect increases with increasing Gr content.
机译:制备了一系列不同的铝-石墨复合材料(Al-Gr),即纯Al,Al-1%Gr,Al-2%Gr和Al-3%Gr。使用光学显微镜研究了这些复合材料的表面,以检查剥落的石墨在铝中的分布。使用循环电势极化(CPP),计时电流法(CA)和电化学阻抗谱(EIS)对在3.5%NaCl溶液中不同的浸入间隔后的纯Al和Al-Gr复合材料进行腐蚀行为。扫描电子显微镜(SEM)和能量色散X射线(EDX)研究也对该研究表示赞赏。腐蚀测试表明,Gr的存在及其含量的增加提高了腐蚀速率,降低了Al的极化电阻。发现在测量前增加试样在氯化物溶液中的浸入时间可以减少一般腐蚀并增加点蚀。SEM/ EDX研究表明,由于存在电化腐蚀,Gr的存在会激活Al的腐蚀,并且这种影响随着Gr含量的增加而增加。

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