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Characteristics of Nickel Boron Coatings prepared by Direct Current Electrodeposition Technique

机译:直流电沉积技术制备的镍硼涂层的特性

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In this research, Ni-B coatings with different boron content (1.85 to 18.63 at.%) were produced by direct current electrodeposition technique and from a bath containing trimethylamineborane (TMAB) at 0.06M. The influence of deposition current density on the composition, surface morphology, grain size, hardness, corrosion resistance and wear properties of the coatings was investigated. Our result found that the boron content in the coatings decreases significantly with increasing deposition current density. The further analysis showed the great influence of boron content on the grain size and hardness of the coating. A maximum hardness of about 954 Hv was obtained for a nanocrystalline Ni- B coating with a boron content of 4.38 at.%, while the amorphous-like Ni-B coating at a boron content of 18.63 at.% has a lower hardness as compared to those nanocrystalline Ni-B coatings. The potentiodynamic polarization measurement showed that the Ni-B coatings had higher corrosion resistance than that of pure nickel coating. Grain size is the main factor affecting corrosion resistance of the coatings. Wear test results show that the wear resistance of Ni-B coatings is governed by the microhardness. An increase in the hardness of the Ni-B coating leads to promotion of the wear resistance.
机译:在这项研究中,采用直流电沉积技术,并从含有0.06M三甲基胺硼烷(TMAB)的镀液中生产出了不同硼含量(1.85至18.63 at。%)的Ni-B涂层。研究了沉积电流密度对涂层成分,表面形貌,晶粒尺寸,硬度,耐蚀性和磨损性能的影响。我们的结果发现,随着沉积电流密度的增加,涂层中的硼含量显着降低。进一步的分析表明硼含量对涂层的晶粒度和硬度有很大的影响。硼含量为4.38 at。%的纳米晶Ni- B涂层的最大硬度约为954 Hv,而硼含量为18.63 at。%的非晶态Ni-B涂层的硬度较那些纳米晶Ni-B涂层。电位极化测量表明,Ni-B涂层的耐蚀性比纯镍涂层高。晶粒尺寸是影响涂层耐腐蚀性的主要因素。磨损测试结果表明,Ni-B涂层的耐磨性受显微硬度的支配。 Ni-B涂层的硬度增加导致耐磨性的提高。

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