Theoretical and Experimental Studies of Adsorption Characteristics of Newly Synthesized Schiff Bases and their Evaluation as Corrosion Inhibitors for Mild Steel in 1 M HCl

摘要

A new class of Schiff base compounds viz., 4,4'-bis(2,4-dihydroxybenzaldeyde) diphenylethanediimine (L1) and 4,4’-bis(4-diethlylaminosalicylaldehyde) diphenylethanediimine (L2) have been synthesized and characterized by spectral techniques using Elemental analysis, FTIR, 1H- NMR and mass spectrometry. The inhibition action on corrosion of the Schiff bases on mild steel in 1 M hydrochloric acid has been studied by the weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods were applied to study the corrosion at different concentrations of inhibitors. The inhibition efficiency has been compared with their parent amine from which the Schiff bases have been derived. The obtained results showed that L1and L2 exhibited good inhibition on mild steel in HCl solution and the inhibition efficiency increased with increasing concentration, reaching a maximum inhibition efficiency of 95.33% and 94.18% designated respectively to L1and L2 at 5x10-4 M and decreased with increasing the temperature. Polarization study clearly suggested that these Schiff’s bases act as mixed-type inhibitors with some cathodic predominance. The adsorption of L1 and L2 obeys Langmuir isotherm. SEM analyses revealed that inhibition occurs due to adsorption of molecules at metal/solution interface. Quantum chemical parameters were calculated using DFT method such as energy gaps support the good inhibiting performance of the two Schiff bases.