Construction of Highly Active Pt/Ni-Fe Layered Double Hydroxide Electrocatalyst towards Methanol Oxidation in Alkaline Medium

摘要

A novel Pt/Ni-Fe layered double hydroxide (Pt/Ni-Fe LDH) electrocatalyst was fabricated by a two-stepfacile process for oxidation of methanol in alkaline medium. It is found that Pt/Ni-Fe LDHelectrocatalyst exhibits higher electrocatalytic activity, better anti-poisoning ability and stability formethanol oxidation comparing to pure Pt black and commercial Pt/C catalyst. Such an enhancement isprobably attributed to the synergistic effect of Ni-Fe LDH and the uniform loading of Pt nanoparticleson the LDH layers. When ionic liquid (IL) was introduced to the composites, the prepared Pt/IL/Ni-FeLDH exhibits even better electrocatalytic behaviors (205.6 mA mg -1 Pt , I f /I b =5.67) than the Pt/Ni-FeLDH. Moreover, the morphology and structure of composites were characterized using scanning electronmicroscope equipped with an energy dispersive X-ray spectrometry, transmission electron microscope,X-ray diffraction, and FT-IR spectra. It is found that the Ni-Fe LDH have a flake-like morphology, themean diameter of Pt nanoparticles in Pt/Ni-Fe LDH and Pt/IL/Ni-Fe LDH electrocatalyst is 4.36 nm and3.09 nm, smaller than that in pure Pt black and commercial Pt/C electrocatalyst (8.70 nm and 6.48 nm).