Characterization of Pure and Pb2+ ion Doped Methylcellulose Based Biopolymer Electrolyte Films: Optical and Electrical Properties

摘要

Pb2+ ion-conducting biopolymer electrolyte films, based on methylcellulose (MC) were prepared,using the solution cast technique. The effect of Pb2+ doping concentration on the optical and electricalproperties of host MC are described in this manuscript. Fourier transform infrared (FTIR) spectraindicated the occurrence of complexation between Pb2+ and biopolymer host in the synthesisbiopolymer-based electrolyte films. Ultraviolet-visible (UV-Vis) spectroscopy accounts for aconsiderable continuous decline in optical band gap and band tail energy, which attributed to theformation of charge-transfer complex and increasing in the crystalline nature of the polymer electrolytefilms, respectively. The dispersion of the refractive index was discussed in term of the single-oscillatormodel. The frequency-dependent electrical conductivity and dielectric constants of the preparedsamples were investigated as a function of temperature and frequency by impedance spectroscopy.Temperature-dependent behavior of the frequency-exponent reveals that the correlated barrier hopping(CBH) model is the most suitable model to describe the conduction mechanism for the present system.The highest value of ion conductivity at ambient temperature was found to be 2.68×10?6 S/m for thepolymer incorporated with 20 wt.% Lead acetate. The non-Debye type relaxation behaviour has beenconfirmed by the asymmetric relaxation peak of the imaginary part of the electric modulus. Thepresent biopolymer electrolyte films were specified as promising materials for electrochemical deviceapplications.