Synthesis and evaluation of carbon nanotubes composite adsorbent for CO2 capture: a comparative study of CO2 adsorption capacity of single-walled and multi-walled carbon nanotubes

摘要

Abstract As a preliminary investigation towards obtaining carbon nanotube composite adsorbent for CO~(2) capture, in this study CO~(2) adsorption performance of three commercial carbon nanotubes (CNTs) one single-walled carbon nanotubes (SWCNTs), and two (2) different multi-walled carbon nanotubes (referred to as A-MWCNTs and B-MWCNTs) were evaluated and compared. The purpose of this study was to compare the different types of CNTs and select the best to serve as the solid anchor in the development of a hydrophobic composite adsorbent material for CO~(2) capture. The N~(2) physi-sorption of the CNTs was conducted to determine their surface area, pore volume and pore size. In addition, morphology and purity of the CNTs were checked with Transmission Electron Microscopy and Raman Spectroscopy, respectively. The CO~(2) adsorption capacity of the CNTs was evaluated using Thermo-gravimetric analysis (TGA) at 1.1?bar, at operating temperature ranged from 25 to 55?°C and at different CO~(2) feed flow rates, in order to evaluate the effects of these variables on the CO~(2) adsorption capacity. The results of CO~(2) adsorption with the TGA show that CO~(2) adsorption capacity for both SWCNTs and MWCNTs was the highest at 25?°C. Changing the CO~(2) flowrates had no significant effect on the adsorption capacity of MWCNTs, but decreasing the CO~(2) flow rate resulted in the enhancement of the CO~(2) adsorption capacity of SWCNTs. Overall, it was found that the SWCNTs displayed the highest CO~(2) adsorption capacity (29.97?gCO~(2)/kg?adsorbent) when compared to the MWCNTs (12.09?gCO~(2)/kg?adsorbent), indicating a 150% increase in adsorption capacity over MWCNTs.