span style="font-size:10.0pt;font-family: "Times New Roman","serif";mso-fareast-font-family:"Times New Roman";mso-bidi-font-family: Mangal;mso-ansi-language:EN-US;mso-fareast-language:EN-US;mso-bidi-language: HI" lang="EN-US"Physico-chemical properties of binary mixtures of tert-butanol with (nitro-, chloro- and bromo-) benzene at 303.15 K and 308.15 K/span

摘要

span style="font-size:10.0pt;font-family: " times="" new="" roman","serif";mso-fareast-font-family:"times="" roman";mso-bidi-font-family:="" mangal;mso-ansi-language:en-us;mso-fareast-language:en-us;mso-bidi-language:="" hi"="" lang="EN-US"The density (span style="font-size:10.0pt;font-family: Symbol;mso-ascii-font-family:" times="" new="" roman";mso-fareast-font-family:"times="" roman";="" mso-hansi-font-family:"times="" roman";mso-bidi-font-family:mangal;mso-ansi-language:="" en-us;mso-fareast-language:en-us;mso-bidi-language:hi;mso-char-type:symbol;="" mso-symbol-font-family:symbol"="" lang="EN-US"img src='http://www.niscair.res.in/jinfo/rho.gif' border=0span style="font-size:10.0pt;font-family: " times="" new="" roman","serif";mso-fareast-font-family:"times="" roman";mso-bidi-font-family:="" mangal;mso-ansi-language:en-us;mso-fareast-language:en-us;mso-bidi-language:="" hi"="" lang="EN-US"), viscosity (span style="font-size:10.0pt;font-family: Symbol;mso-ascii-font-family:" times="" new="" roman";mso-fareast-font-family:"times="" roman";="" mso-hansi-font-family:"times="" roman";mso-bidi-font-family:mangal;mso-ansi-language:="" en-us;mso-fareast-language:en-us;mso-bidi-language:hi;mso-char-type:symbol;="" mso-symbol-font-family:symbol"="" lang="EN-US"img src='/image/spc_char/Etta.gif' border=0span style="font-size:10.0pt;font-family: " times="" new="" roman","serif";mso-fareast-font-family:"times="" roman";mso-bidi-font-family:="" mangal;mso-ansi-language:en-us;mso-fareast-language:en-us;mso-bidi-language:="" hi"="" lang="EN-US") and speed of sound (iu/i) of three binary liquid mixtures of tert-butanol with (nitro-, chloro- and bromo-) benzene have been measured over the entire composition range at 303.15 K, 308.15 K and atmospheric pressure. From the experimental data, excess molar volume (iV/isupE/sup), isentropic compressibility (?osubs/sub), excess Gibbs free energy of activation (span style="font-size:10.0pt;font-family:Symbol; mso-ascii-font-family:" times="" new="" roman";mso-fareast-font-family:"times="" roman";="" mso-hansi-font-family:"times="" roman";mso-bidi-font-family:mangal;mso-ansi-language:="" en-us;mso-fareast-language:en-us;mso-bidi-language:hi;mso-char-type:symbol;="" mso-symbol-font-family:symbol"="" lang="EN-US"img src='/image/spc_char/delta.gif' border=0ispan style="font-size:10.0pt;font-family: " times="" new="" roman","serif";mso-fareast-font-family:"times="" roman";mso-bidi-font-family:="" mangal;mso-ansi-language:en-us;mso-fareast-language:en-us;mso-bidi-language:="" hi"="" lang="EN-US"G/span/ispan style="font-size:10.0pt;font-family:" times="" new="" roman","serif";="" mso-fareast-font-family:"times="" roman";mso-bidi-font-family:mangal;="" mso-ansi-language:en-us;mso-fareast-language:en-us;mso-bidi-language:hi"="