Heterogeneous uptake of gaseous hydrogen peroxide by Gobi and Saharan dust aerosols: a potential missing sink for Hsub2/subOsub2/sub in the troposphere

摘要

pstrongAbstract./strong The first direct laboratory measurements of gaseous hydrogen peroxide uptake by authentic Gobi and Saharan dust aerosol particles as a function of relative humidity (RH) have been carried out in an entrained aerosol flow tube coupled to a chemical ionization mass spectrometer. Gobi dust shows uptake coefficients, γsubHsub2/sub Osub2/sub/sub = (3.33±0.26) ??10sup−4/sup at 15% RH rising to γsubHsub2/sub Osub2/sub/sub = (6.03±0.42) ??10sup−4/sup at 70% RH; the corresponding values for Saharan dust are systematically higher (γsubHsub2/sub Osub2/sub/sub = (6.20±0.22)×10sup−4/sup at 15% RH rising to γsubHsub2/sub Osub2/sub/sub = (9.42±0.41) ??10sup−4/sup at 70% RH). High resolution X-ray photoelectron spectroscopy (XPS) measurements of the surface chemical composition of the two mineral dust samples together with published water adsorption isotherms of their principal constituents enables rationalization of these observations, which are relevant to nighttime tropospheric chemistry. A box model study performed by incorporating the experimentally determined data set reveals that uptake of Hsub2/subOsub2/sub onto dust can be an important loss process for this species which has been, until now, poorly constrained./p.