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Universal Scattering of Ultracold Atoms and Molecules in Optical Potentials

机译:超冷原子和分子在光势中的通用散射

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Universal collisions describe the reaction of molecules and atoms as dominated by long-range interparticle interactions. Here, we calculate the universal inelastic rate coefficients for a large group of ultracold polar molecules in their lower ro-vibrational states colliding with one of their constituent atoms. The rate coefficients are solely determined by values of the dispersion coefficient and reduced mass of the collisional system. We use the ab initio coupled-cluster linear response method to compute dynamic molecular polarizabilities and obtain the dispersion coefficients for some of the collisional partners and use values from the literature for others. Our polarizability calculations agree well with available experimental measurements. Comparison of our inelastic rate coefficients with results of numerically exact quantum-mechanical calculations leads us to conjecture that collisions with heavier atoms can be expected to be more universal.
机译:普遍碰撞将分子和原子的反应描述为远程粒子间相互作用所主导。在这里,我们计算了一大批处于较低ro振动状态的超冷极性分子与它们的组成原子之一发生碰撞的通用非弹性速率系数。速率系数仅由色散系数和碰撞系统质量降低的值确定。我们使用从头算起的耦合簇线性响应方法来计算动态分子极化率,并获得某些碰撞对象的色散系数,而使用其他文献中的值。我们的极化率计算与可用的实验测量结果非常吻合。将我们的非弹性速率系数与精确的量子力学计算结果进行比较,可以推测,与较重原子的碰撞可能会更加普遍。

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