Kinetics and Mechanism of the Redox Reaction Between Pt(IV) Complex Ions and Sodium Thiosulfate in Aqueous Solution. Part II: Neutral and Alkaline Solution/ Kinetyka I Mechanizm Reakcji Redoks Pomi?dzy Jonami Kompleksowymi Pt(Iv) I Tiosiarczanem Sodu W Roztworze Wodnym. Cz??? II: Roztwór Oboj?tny I Zasadowy

摘要

In this work, spectrophotometric studies on the kinetics and mechanism of the reaction between [PtCl6]2- complex ions and sodium thiosulfate, in neutral (pH = 7) and alkaline (p = 12) solution, were carried out. Applying different conditions, the influence of initial concentrations of reductant and platinum(IV) complex ions as well as the influence of temperature and ionic strength on the rate constant, was experimentally determined. From the obtained results, the molecularity, the order and the value of enthalpy and entropy of activation of the reaction, were experimentally determined. It was found that in both cases the reduction reaction is relatively slow and in the studied conditions the second-order rate constant changes from 2.92 : 10-2 to 0.40 M-1:s-1 at pH = 7, and from 3.84 : 10-2 to 1.55 M-1s-1 at pH = 12. Additionally, depending on the pH, different mechanism of the reaction is present. However, regardless on the studied system the only platinum(II) chloride complex ions are the final product of the redox reaction.