Hydrogenated-Graphene-Encapsulated Graphene: A Versatile Material for Device Applications

摘要

Graphene and its heterostructures exhibit interesting electronic properties and are explored for quantum spin Hall effect (QSHE) and magnetism-based device applications. In present work, we propose a heterostructure of graphene encapsulated by hydrogenated-graphene, which could be a promising candidate for a variety of device applications. We have carried out DFT calculations on this system to check its feasibility to be a versatile material. We found that electronic states of multilayer pristine graphene, especially the Dirac cone, an important feature to host QSHE, can be preserved by sandwiching it by fully hydrogenated graphene. The interference of electronic states of hydrogenated graphene was insignificant with those of graphene. States of graphene were also found to be stable upon application of an electric field up to ±2.5 Vm. For device applications, multilayer graphene or its heterostructures are required to be deposited on a substrate, which interacts with the system opening up a gap at the Dirac cone making it less suitable for QSHE applications, and hydrogenated graphene can prevent it. Magnetization in these hydrogenated-graphene-sandwiched graphene systems may be induced by creating vacancies or distortions in hydrogenated graphene, which was found to have a minimal effect on graphene’s electronic states, thus providing an additional degree of manipulation. We also performed a set of calculations to explore its applicability for detecting some molecules. Our results on trilayer graphene encapsulated by hydrogenated graphene indicate that all these observations can be generalized for systems with a larger number of graphene layers, indicating that multilayer graphene sandwiched between two hydrogenated graphene is a versatile material that can be used in QSHE and sensor devices.