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Enhanced Antifouling Feed Spacer Made from a Carbon Nanotube–Polypropylene Nanocomposite

机译:由碳纳米管-聚丙烯纳米复合材料制成的增强型防污进料垫片

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Spacers are widely used in membrane technologies to reduce fouling and concentration polarization. Fouling can start from the spacer surface and grow, thereby reducing flux, selectivity, and operation lifetime. Fluorescein isothiocyanate labeled bovine serum albumin was used for fouling studies and observed during cross-flow filtration operation for up to 144 h. Here, we mixed carbon nanotubes (CNTs) and polypropylene (PP) to make a spacer with better antifouling than plain PP spacers. The fouling process was observed by scanning electron microscopy and monitored in situ by fluorescence microscopy. Molecular dynamics simulations show that bovine serum albumin has a lower interaction energy with the nanocomposite CNTs/PP spacer than with the plain PP. The findings are relevant for the development of spacers to improve the operation lifetime of membranes in filtration technologies.
机译:隔离膜广泛用于膜技术中,以减少结垢和浓差极化。结垢可能会从垫片表面开始并逐渐增长,从而降低通量,选择性和使用寿命。异硫氰酸荧光素标记的牛血清白蛋白用于结垢研究,并在错流过滤操作中观察长达144小时。在这里,我们将碳纳米管(CNT)和聚丙烯(PP)混合在一起,制成了比普通PP垫片具有更好的防污性的垫片。通过扫描电子显微镜观察结垢过程,并通过荧光显微镜原位监测结垢过程。分子动力学模拟表明,牛血清白蛋白与纳米复合CNTs / PP间隔基的相互作用能比普通PP低。该发现与间隔物的开发有关,以改善过滤技术中膜的使用寿命。

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