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Interfacially Interactive Ternary Silver-Supported Polyaniline/Multiwalled Carbon Nanotube Nanocomposites for Catalytic and Antibacterial Activity

机译:界面相互作用的三元银载聚苯胺/多壁碳纳米管纳米复合材料的催化和抗菌活性。

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摘要

Herein, a protocol strategy has been designed for the preparation of ternary silver nanoparticles-supported polyaniline multiwalled carbon nanotube (Ag NPs–PANI/MWCNT) nanocomposites with a chemical interaction for catalytic and antibacterial activity. The morphological study confirmed that Ag NPs were immobilized on the surface of PANI, and afterward, Ag NPs–PANI were mixed with the MWCNTs. The X-ray diffraction technique revealed the face-centered cubic structure of Ag NPs, and the X-ray photoelectron spectroscopy study revealed the chemical constituent and signature of π–π* and C–N interactions in the nanocomposites. The ternary Ag NPs–PANI/MWCNTs nanocomposites have the apparent rate of reaction (Kapp) as 5.4 × 10–3 s–1, higher than binary nanocomposites for catalytic reduction of 4-nitrophenol to 4-aminophenol at room temperature. Antibacterial activity of Ag NPs–PANI/MWCNT nanocomposites is higher against pathogenic bacteria. Thereafter, because of multifold applications of ternary nanocomposites, they have a broad scope in the field of environmental and healthcare sectors.
机译:在本文中,已设计了一种协议策略,用于制备具有化学相互作用的三元银纳米颗粒支撑的聚苯胺多壁碳纳米管(Ag NPs-PANI / MWCNT)纳米复合材料,具有催化和抗菌活性。形态学研究证实,Ag NPs被固定在PANI的表面,然后将Ag NPs–PANI与MWCNTs混合。 X射线衍射技术揭示了Ag NP的面心立方结构,X射线光电子能谱研究揭示了纳米复合材料中π–π *和C–N相互作用的化学成分和特征。 Ag三元NPs-PANI / MWCNTs纳米复合材料的表观反应速率(Kapp)为5.4×10-3 s-1,高于室温下催化将4-硝基苯酚还原为4-氨基苯酚的二元纳米复合材料。 Ag NPs-PANI / MWCNT纳米复合材料对病原菌的抗菌活性更高。此后,由于三元纳米复合材料的广泛应用,它们在环境和医疗保健领域具有广阔的范围。

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