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Experimentálne odstraňovanie antimónu z?banskych v?d (opustené Sb lo?isko Popro?, vychodné Slovensko)

机译:从科学实验中去除锑(斯洛伐克东部废弃的Sb矿床Popro?)

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In the process of experimental testing of antimony elimination from mine water that was sampled at the abandoned Sb deposit at the Eastern Slovakia, three remediation techniques in the form of column experiments were used: removal of Sb by activated carbon; GEH sorbent (granulated Fe(OH)3?with content of?βFeOOH and H2O) and the ion exchange resin process with the use of single strongly acidic catex Amberlite IR-120 (Na+?cycle) and a combination of catex and weakly basic annex Purolite A-100 (OH-?cycle). Popro? village, which is located near the abandoned Sb deposit, is currently suffering from a lack of a permanent source of drinking water. However, if the decontaminated mine water was adequately treated it could serve as an alternative source of drinking water at the Popro? locality. Sample of tested mine water contained 120 μg.l-1?of Sb that represents 24 times more than is the limit for Sb concentration (5 μg.l-1) in drinking water as determined by SR?Government Regulation No.?496/2010 Coll. Activated carbon in the process of Sb elimination from the tested mine water showed the lowest effectiveness (20%). Using of the single catex resulted in the 41 % efficiency and using of combination of the catex and annex resulted in 98 % efficiency in the process of Sb removal from the tested mine water. The GEH sorbent showed also high ability (efficiency 98 %) of Sb elimination. Treated mine water (after use of GEH sorbent) was hygienically stabilised with the use of disinfection reagent in the form of 0.3?%?ClO2?solution and the water analysis were performed in the range corresponding to the drinking water analysis. From the obtained experimental results it can be concluded that the present mine water after adequate treatment can be potentially suitable and serve as a source of drinking water at studied locality.
机译:在从斯洛伐克东部废弃的Sb矿床取样的矿井水中消除锑的实验测试过程中,采用了三种以柱实验形式进行修复的技术:用活性炭去除Sb;通过活性炭去除Sb;以及通过柱净化的方法。 GEH吸附剂(粒状Fe(OH)3?含量为?βFeOOH和H2O)和离子交换树脂工艺,使用单一强酸性Catex Amberlite IR-120(Na +?循环)以及catex和弱碱性附件的组合Purolite A-100(OH-循环)。 Popro?该村庄位于被遗弃的锑矿附近,目前正缺乏永久的饮用水源。但是,如果对去污染的矿井水进行了适当的处理,它可以作为Popro的替代饮用水来源吗?地区。被测矿井水样品中含有120μg.l-1?的Sb,比SR?政府法规No.496 /确定的饮用水中Sb浓度极限(5μg.l-1)高24倍。 2010 Coll。从测试的矿井水中去除Sb的过程中,活性炭的有效性最低(20%)。在测试的矿井水中除Sb的过程中,使用单个catex的效率为41%,使用catex和附件的效率为98%。 GEH吸附剂还具有很高的除Sb能力(效率98%)。处理过的矿井水(使用GEH吸附剂后)通过使用0.3 %% ClO2?溶液形式的消毒剂进行卫生稳定处理,并在与饮用水分析相对应的范围内进行水分析。从获得的实验结果可以得出结论,经过适当处理的现有矿井水可能是合适的,并且在所研究的地方可以作为饮用水水源。

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