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首页> 外文期刊>Croatica chemica acta >Synthesis, Crystal Structures and Properties of New Chloroniobium Cluster Hydroxides with Co-ordinated and Non-coordinated OHsup-/sup Groups. The Presence of Hsub3/subOsub2/sub Intercluster Bridges
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Synthesis, Crystal Structures and Properties of New Chloroniobium Cluster Hydroxides with Co-ordinated and Non-coordinated OHsup-/sup Groups. The Presence of Hsub3/subOsub2/sub Intercluster Bridges

机译:具有配位和非配位OH -基团的新型氯铌团簇氢氧化物的合成,晶体结构和性能。 H 3 O 2 簇间桥的存在

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摘要

The isostructural, trigonal clusters of the composition [Nb6Cl12(H20)6](0H)2 l/4CH30H ? 6H20 1 and [Nb6Cl12(H20)6](OH)2 -6H20 2 have been isolated from alkaline solutions of [NbgClj^]2* cluster in alcohol/water (1:3) in the presence of...
机译:组成[Nb6Cl12(H20)6](0H)2 l /4CH30H≤δ的同构三角形簇。在乙醇/水(1:3)存在下,从[NbgCl2 ^] 2 *团簇的碱性溶液中分离出6H20 1和[Nb6Cl12(H20)6](OH)2 -6H20 2。

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