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Experimental Evaluation of Polyester and Epoxy–Polyester Powder Coatings in Aggressive Media

机译:侵蚀性介质中聚酯和环氧-聚酯粉末涂料的实验评估

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Protective coatings are the most widely used corrosion protection method for construction materials in different environmental conditions. They isolate metals from aggressive media, making the structure more durable. Today, alongside good anti-corrosive properties, coatings need to be safe for the environment and harmless to those who apply them. The high volatile organic compound (VOC) content in conventional solvent-borne coatings presents a huge ecological problem. A solution for indispensable solvent emission reduction is the application of powder coatings. This study evaluates the corrosion performance and surface morphology of polyester and epoxy–polyester powder coatings. Electrochemical impedance spectroscopy (EIS), open circuit potential (OCP) measurement, salt spray chamber and humidity chamber testing followed by adhesion testing were used to investigate the protective properties of powder coatings. Scanning electron microscope (SEM) with energy-dispersive X-ray spectroscopy (EDX) was used to analyse the surface morphology and chemical composition, whereas the microstructure and coating uniformity were determined by optical microscope examination. The research revealed a negative influence of coating surface texture on coating thickness and consequently a lack of barrier and adhesion properties. The epoxy–polyester powder coating showed a better performance than the polyester coating. All tested coatings showed uniform structure.
机译:防护涂料是在不同环境条件下对建筑材料使用最广泛的腐蚀防护方法。它们将金属与侵蚀性介质隔离开来,使结构更加耐用。如今,除了具有良好的防腐蚀性能外,涂料还需要对环境安全并且对施涂者无害。传统溶剂型涂料中的高挥发性有机化合物(VOC)含量带来了巨大的生态问题。减少不可或缺的溶剂排放的解决方案是粉末涂料的应用。这项研究评估了聚酯和环氧-聚酯粉末涂料的腐蚀性能和表面形态。电化学阻抗谱(EIS),开路电位(OCP)测量,盐雾室和湿度室测试,然后进行附着力测试,用于研究粉末涂料的防护性能。扫描电子显微镜(SEM)和能量色散X射线光谱(EDX)用于分析表面形态和化学成分,而显微结构和涂层均匀性则通过光学显微镜检查来确定。研究发现涂层表面纹理对涂层厚度有负面影响,因此缺乏阻隔性和粘附性。环氧-聚酯粉末涂料比聚酯涂料具有更好的性能。所有测试的涂层均显示出均匀的结构。

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