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Ultrasonic studies on sodium-doped LaMnO3 perovskite material

机译:钠掺杂LaMnO3钙钛矿材料的超声研究

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La_(1?x )Na_(x )MnO_(3) perovskite manganite in the form of circular pellets was prepared with the composition of x ?=?0.10, 0.15 and 0.20 by the solid-state reaction technique. To confirm the crystalline nature of the samples, X-ray diffraction patterns of the samples were obtained. It is found that the samples have a rhombohedral structure with R3c space group. Particle size was determined from the obtained scanning electron microscope images. Ultrasonic velocity and the attenuation measurements were carried out on the samples employing the transmission technique in the temperature range from 300 to 400?K. The anomalous behaviour obtained in the ultrasonic measurements was used to explore the transition temperature of the prepared La_(1?x )Na_(x )MnO_(3) perovskite samples. The temperatures 320, 328 and 334?K are the ferromagnetic to paramagnetic phase transition temperatures of the samples x ?=?0.10, 0.15 and 0.20, respectively.
机译:通过固相制备组成为圆形颗粒的La_(1αx)Na_(ix)MnO_(3)钙钛矿锰矿,其圆形颗粒的组成为-x≥0.10、0.15和0.20。状态反应技术。为了确认样品的晶体性质,获得了样品的X射线衍射图。发现样品具有R3c空间群的菱面体结构。从获得的扫描电子显微镜图像确定粒径。在300至400?K的温度范围内,采用透射技术对样品进行超声波速度和衰减测量。在超声测量中获得的异常行为被用来探索所制备的La_(1αx)Na_(ix)MnO_(3)钙钛矿样品的转变温度。温度320、328和334≤K分别是样品的铁磁性到顺磁性的相变温度×x = 0.10、0.15和0.20。

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