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Mechanical Properties of TiO2 Reinforced Polystyrene- Modified Unsaturated Polyester

机译:TiO2增强的聚苯乙烯改性的不饱和聚酯的机械性能

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The aim of current research is carrying out some modifications on the properties of resin material Unsaturated Polyester (UP) by adding thermoplastic material Polystyrene (PS) in different weight ratios included 4%, 8%, 12%,14%,16%,20% and 24% was used to prepare binary polymer blend. The best ratio was selected in terms of the homogeneity case between the two polymers and according to compression strength for all prepared specimens. The ratio 92/8 wt.% of UP/PS blend was selected and reinforced with different particle volume fractions of 1%, 3%, 5% and 7% using of TiO 2 particles. The composite materials with unsaturated polyester-polystyrene matrix properties were evaluated by conducting the mechanical tests which included compression, hardness and impact resistance. Results of compression test showed that the compression strength decreases as polystyrene percentage (PS) increases. While the TiO 2 an addition has helped in balancing the original compression strength reduction up to 3% vol. of TiO 2 and then the strength decreases. The results confirmed that the best enhancement is of 3% vol. of TiO 2 considering compression strength and impact. The SEM results indicate that the polystyrene particles have good distribution through UP, this distribution of smaller particles is responsible for lower crack growth. The SEM results of composites specimen show the TiO 2 particles have good distribution through the matrix up to 3% vol., the mechanical properties beyond 3% vol. decreased due to the presence of particle agglomerations.
机译:当前研究的目的是通过添加不同重量比的热塑性材料聚苯乙烯(PS)来对树脂材料不饱和聚酯(UP)的性能进行一些修改,包括4%,8%,12%,14%,16%,20 %和24%用于制备二元聚合物共混物。根据两种聚合物之间的均质情况,并根据所有制备样品的抗压强度,选择最佳比例。选择比例为92/8重量%的UP / PS共混物,并使用TiO 2颗粒以1%,3%,5%和7%的不同颗粒体积分数增强。通过进行包括压缩,硬度和抗冲击性在内的机械测试,对具有不饱和聚酯-聚苯乙烯基体性能的复合材料进行了评估。压缩试验结果表明,随着聚苯乙烯百分比(PS)的增加,压缩强度降低。 TiO 2的加入有助于平衡原始压缩强度降低至3%vol。 TiO 2的含量然后强度降低。结果证实最好的增强是3%vol。考虑压缩强度和冲击的TiO 2的含量。 SEM结果表明,聚苯乙烯颗粒通过UP具有良好的分布,较小颗粒的这种分布导致较低的裂纹扩展。复合材料样品的SEM结果表明TiO 2颗粒在基体中的分布良好,至多3%vol。,机械性能超过3%vol。由于存在颗粒团聚而减少。

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