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Alkali Activated Eco-friendly Metakaolin/Slag Geopolymer Building Bricks

机译:碱活化的环保偏高岭土/矿渣地质聚合物建筑砖

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Alkali activation of alumino-silicate materials is a complex chemical process evolving dissolution of raw materials, transportation or orientation and polycondensation of the reaction products. This study explores the physico-mechanical characteristics of geopolymer bricks using eco-friendly slag/metakaolin binder. Alkaline activation of slag – metakaolin binder of geopolymer brick results in formation of C-A-S-H as well as N-A-S-H gel, which adopts different structures depending on the nature of the alkaline activator. Activators used are 10% NaOH solution in addition to 5% liquid sodium silicate both used from the total binder weight), Geopolymer bricks prepared by partial binder substitution of metakaolin (fired kaolin) by water cooled slag in the ratio from 0 up to 100 %, while the used fine sand(passing 1 mm) in the ratio of 15% from the total weight. The properties of the produced geopolymer bricks have been studied through measurement of compressive strength, water absorption, FTIR, XRD and SEM imaging. Results demonstrate the possibility of substitution of metakaolin by water cooled amorphous slag materials in producing geopolymer bricks with superior properties where an increase in mechanical strength with water cooled slag increase up to 40 % was noticed giving compressive strength values exceed 70 MPa which can be used for production of heavy duty bricks which can be applied in a severe weathering condition as well as special purposes building applications, however further increase results in lowering strength values as a but still exceed 30 MPa after 28 days of hydration.
机译:铝硅酸盐材料的碱活化是一个复杂的化学过程,涉及原料的溶解,反应产物的运输或取向和缩聚。这项研究探索了使用环保的矿渣/偏高岭土粘合剂的地聚合物砖的物理-机械特性。矿渣的碱活化-地质聚合物砖的偏高岭土粘合剂导致形成C-A-S-H以及N-A-S-H凝胶,凝胶根据碱性活化剂的性质采用不同的结构。使用的活化剂是10%的NaOH溶液,以及5%的液态硅酸钠(均从总粘合剂重量中使用),通过水冷炉渣以0至100%的比例用水冷炉渣部分替代偏高岭土(燃烧的高岭土)而制备的地质聚合物砖,而所使用的细砂(超过1毫米)的比例为总重量的15%。通过测量抗压强度,吸水率,FTIR,XRD和SEM成像来研究所生产的地质聚合物砖的性能。结果表明,在生产具有优异性能的地聚合物砖时,用水冷无定形炉渣材料替代偏高岭土的可能性强,其中水冷炉渣的机械强度提高了40%,并且抗压强度值超过70 MPa,可用于生产可在恶劣气候条件下以及特殊用途建筑应用中使用的重型砖,但是进一步增加会导致强度值降低,但在水合28天后仍会超过30 MPa。

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