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Adsorption of Sn(Ⅱ) on expanded graphite: kinetic and equilibrium isotherm studies

机译:膨胀石墨上Sn(Ⅱ)的吸附:动力学和平衡等温线研究

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摘要

Expanded graphite (EG) was prepared by microwave irradiation at 1000 W for 60s. EG is a novel adsorbent for Sn(Ⅱ) adsorption and its ability to remove Sn(Ⅱ) ions from wastewater was investigated. To characterize the adsorptive characteristics of the produced EG, the microstructures of the resultant EG were observed using scanning electron microscopy. Chemical characterization of the surface resultant EG was studied by Fourier transform infrared spectroscopy. The effects of pH, adsorbent dosage, initial concentration, temperature, and contact time on the adsorption surface were studied using the batch process technique. The data fitted with the Langmuir equilibrium isotherm and pseudo-second-order kinetics. The maximum adsorption capacity of Sn(Ⅱ) on the resultant EG was 378.78 mg g~(-1).
机译:通过在1000 W的微波辐射下60s制备膨胀石墨(EG)。 EG是一种新型的Sn(Ⅱ)吸附剂,研究了其去除废水中Sn(Ⅱ)离子的能力。为了表征所产生的EG的吸附特性,使用扫描电子显微镜观察所得EG的微观结构。通过傅立叶变换红外光谱研究了表面生成的EG的化学表征。采用间歇法研究了pH,吸附剂用量,初始浓度,温度和接触时间对吸附表面的影响。符合Langmuir平衡等温线和拟二阶动力学的数据。 Sn(Ⅱ)对所得EG的最大吸附量为378.78 mg g〜(-1)。

著录项

  • 来源
    《Desalination and water treatment》 |2014年第3期|283-292|共10页
  • 作者单位

    Research Center of Analysis & Measurement, Donghua University, 2999 North Renmin Road, Shanghai 201620, China,School of Environmental Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai 201620, China;

    School of Environmental Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai 201620, China;

    School of Environmental Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai 201620, China;

    School of Environmental Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai 201620, China;

    School of Environmental Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai 201620, China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Adsorption; Expanded graphite; Stannum adsorption; Isotherm;

    机译:吸附;膨胀石墨;锡吸附等温线;

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