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Synthesis of polyaspartic acid/2-amino-2-methyl-1,3-propanediol graft copolymer and evaluation of its scale inhibition and corrosion inhibition performance

机译:聚天冬氨酸/ 2-氨基-2-甲基-1,3-丙二醇接枝共聚物的合成及其阻垢缓蚀性能的评价

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摘要

Polyaspartic acid/2-amino-2-methyl-1,3-propanediol graft copolymer, a novel non-phosphorus scale and corrosion inhibitor, was synthesized and characterized by infrared spectroscopy. Its performance was evaluated by static scale inhibition method and dynamic corrosion testing. It was found that the graft copolymer showed excellent inhibition ability against CaCO3, CaSO4, and Ca-3(PO4)(2) scales and a definite inhibition corrosion performance as well. The inhibition efficiency was close to 99.9% against CaCO3, CaSO4, and Ca-3(PO4)(2) when the inhibitor was at an appropriate concentration. The inhibitor had still possessed higher antiscale efficiency against CaCO3 with increasing concentration of Ca2+ and heating time. In addition, The graft copolymer could change the structure of crystals CaCO3, CaSO4, and Ca-3(PO4)(2) by observation of scanning electron microscopy.
机译:合成了一种新型的无磷阻垢缓蚀剂聚天冬氨酸/ 2-氨基-2-甲基-1,3-丙二醇接枝共聚物,并通过红外光谱对其进行了表征。通过静态水垢抑制方法和动态腐蚀测试评估其性能。发现该接枝共聚物对CaCO3,CaSO4和Ca-3(PO4)(2)结垢表现出优异的抑制能力,并且还具有一定的抑制腐蚀性能。当抑制剂处于适当的浓度时,对CaCO3,CaSO4和Ca-3(PO4)(2)的抑制效率接近99.9%。随着Ca2 +浓度的增加和加热时间的延长,该抑制剂对CaCO3的阻垢效果仍然更高。此外,通过扫描电子显微镜观察,接枝共聚物可以改变晶体CaCO3,CaSO4和Ca-3(PO4)(2)的结构。

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