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The effect of operational parameters in the photocatalytic activity of synthesized Mg/ZnO-SnO2 nanoparticles

机译:操作参数对合成的Mg / ZnO-SnO2纳米粒子光催化活性的影响

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In this study, ZnO-SnO2 nanoparticles were prepared using the co-precipitation method, and then to reach higher photocatalytic activity, Mg was impregnated onto the prepared nanoparticles. The results of BET analysis indicated that compared to pure ZnO-SnO2, Mg/ZnO-SnO2 nanoparticles had a higher specific surface area. The photocatalytic performance of synthesized samples was monitored by degradation rate of Methyl Orange (MO) as a probe pollutant under UV light irradiation. In order to get more information for optimization of photocatalytic activity, the effect of various operational parameters (i.e. catalyst dosage, MO concentration, pH, and light intensity) were investigated. The results revealed that the highest removal percentage of MO was achieved with 800mg L-1 of Mg/ZnO-SnO2, 10mg L-1 of MO at pH=4.5, and light intensity of 62.2Wm(-2). The synthesized samples demonstrated superior photocatalytic activity than TiO2-P25 nanoparticles.
机译:在这项研究中,使用共沉淀法制备了ZnO-SnO2纳米颗粒,然后为了达到更高的光催化活性,将Mg浸渍在制备的纳米颗粒上。 BET分析的结果表明,与纯ZnO-SnO2相比,Mg / ZnO-SnO2纳米粒子具有更高的比表面积。通过在紫外线照射下作为探针污染物的甲基橙(MO)的降解速率来监测合成样品的光催化性能。为了获得更多信息,以优化光催化活性,研究了各种操作参数(即催化剂用量,MO浓度,pH和光强度)的影响。结果表明,在800mg L-1的Mg / ZnO-SnO2、10mg L-1的pH = 4.5的MO和62.2Wm(-2)的光强度下,MO的去除率最高。合成样品显示出比TiO2-P25纳米颗粒更好的光催化活性。

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