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Nano-TiO2-loaded activated carbon fiber composite for photodegradation of a textile dye

机译:纳米二氧化钛负载活性炭纤维复合材料对纺织品染料的光降解

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An activated carbon fiber (ASC) synthesized from silk cotton fiber had been converted into a photocatalyst by loading nano-titanium dioxide (TiO2) [in anatase and rutile form] onto ASC. This novel photocatalyst (ASC-TiO2) was found to be active in UV and visible region of electromagnetic spectrum, and tested for its effectiveness in the removal of organic pollutants from industrial wastewater and effluents. In this study, heterogeneous photocatalytic decomposition of methylene blue (MB)-predominantly a textile dyestuff, using the catalyst -ASC-TiO2 had been found to be effective owing to the decomposition of organic pollutants into various harmless simple compounds like CO2 and H2O. Further studies were also conducted to optimize the operating conditions of this treatment by keeping initial dye concentration, catalyst load, and pH values as the causative variables. The results indicated that the catalyst was effective in alkaline medium and enhanced photodegradation of MB by ASC-TiO2 was well explained by pseudo-first-order kinetics.
机译:通过将纳米二氧化钛(TiO2)[锐钛矿和金红石形式]负载到ASC上,将由丝棉纤维合成的活性炭纤维(ASC)转化为光催化剂。发现这种新型光催化剂(ASC-TiO2)在紫外线和电磁光谱的可见光区域具有活性,并测试了其从工业废水和废水中去除有机污染物的有效性。在这项研究中,由于有机污染物分解成各种无害的简单化合物(例如CO2和H2O),因此使用催化剂-ASC-TiO2对亚甲基蓝(MB)-主要是纺织染料进行了非均相光催化分解是有效的。通过保持初始染料浓度,催化剂负载和pH值作为原因变量,还进行了进一步研究以优化该处理的操作条件。结果表明,该催化剂在碱性介质中是有效的,伪一级反应动力学很好地解释了ASC-TiO2对MB的增强光降解作用。

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