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Column studies on the removal of dissolved organic carbon, turbidity and heavy metals from stormwater using granular activated carbon

机译:使用粒状活性炭去除雨水中溶解的有机碳,浊度和重金属的专栏研究

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摘要

Stormwater pollutants have the capacity to damage aquatic environments if they are discharged untreated. Suspended solids (turbidity), dissolved organic carbon (DOC) and heavy metals removal from stormwater were investigated in batch and fixed-bed column experiments. Field studies revealed that turbidity and DOC in stormwater were effectively removed at filtration velocities of 5, 10 and 11.5m/h using a 100cm high granular activated carbon (GAC) filter column. At the higher filtration velocities of 10 and 11.5m/h, adding a pre-treatment 100cm high anthracite filter column further improved DOC and turbidity removal. Batch and column laboratory adsorption experiments at pH 6.5-7.2 using GAC showed that the order of removal efficiency for solutions containing single and mixed metals was Pb, Cu>Zn>Ni, Cd. This order was related to the solubility product and first hydrolysis constants of these metals' hydroxides. This study confirmed that GAC filter is effective in removing turbidity, DOC and heavy metals from stormwater.
机译:如果雨水污染物未经处理就排放,它们有能力破坏水生环境。在分批和固定床色谱柱实验中研究了悬浮固体(浊度),溶解有机碳(DOC)和从雨水中去除的重金属。现场研究表明,使用100cm高粒状活性炭(GAC)过滤柱,以5、10和11.5m / h的过滤速度有效去除了雨水中的浊度和DOC。在10和11.5m / h的较高过滤速度下,添加预处理的100cm高无烟煤过滤柱可进一步改善DOC和除浊度。使用GAC在pH 6.5-7.2的分批和柱实验室吸附实验表明,对于含有单金属和混合金属的溶液,去除效率的顺序为Pb,Cu> Zn> Ni,Cd。该顺序与这些金属的氢氧化物的溶解度积和第一水解常数有关。这项研究证实,GAC过滤器可有效去除雨水中的浊度,DOC和重金属。

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