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Influence of Ce surface treatments on corrosion behaviour of A3xx.x/SiCp composites in 3.5 wt.%NaCl

机译:Ce表面处理对3.5wt。%NaCl中A3xx.x / SiCp复合材料腐蚀行为的影响

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摘要

The influence of silicon carbide particles (SiCp) proportion and matrix composition on aluminium metal matrix composites A3xx.x/SiCp modified by cerium-based conversion or electrolysis coating was evaluated in 3.5 wt.% NaCl at 22℃ using potentiodynamic polarization and gravimetric measurements. Ce-treated surfaces presented better corrosion behaviour in chloride media than original composite surfaces without treatment. Both treatments preferentially covered the intermetal-lic compounds and SiCp. The electrolysis afforded a higher degree of protection than conversion treatment because the coating was more extensive. Coating micro structure and nature of corrosion products were analysed by scanning electron and atomic force microscopy (SEM, AFM) and low angle X-ray diffraction (XRD).
机译:采用电位动力学极化法和重量分析法,在22℃,3.5%(重量)的NaCl溶液中,评价了碳化硅颗粒(SiCp)的比例和基体组成对铈基转化或电解涂层改性铝金属基复合材料A3xx.x / SiCp的影响。经Ce处理的表面在氯化物介质中的腐蚀行为要比未经处理的原始复合材料表面好。两种处理都优先覆盖金属间化合物和SiCp。电解比转化处理提供了更高的保护度,因为涂层更广泛。通过扫描电子和原子力显微镜(SEM,AFM)和低角度X射线衍射(XRD)分析了涂层的微观结构和腐蚀产物的性质。

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