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Electrochemical corrosion behavior of carbon steel under dynamic high pressure H_2S/CO_2 environment

机译:动态高压H_2S / CO_2环境下碳钢的电化学腐蚀行为

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摘要

Through the design of experimental setup, the electrochemical corrosion behavior of carbon steel under dynamic high pressure of H_2S/CO_2 environment was studied by in situ electrochemical measurements and weight loss measurements. Computational fluid dynamics (CFD) was also performed to simulate the flow velocity and shear stress on specimen surface. The results show that both the anodic and catho dic processes are activation controlled. The impedance spectra are characterized by double capacitive semicircles. The in situ electrochemical measurements are in accordance with the CFD simulation of flow velocity and shear stress on the specimen surface.
机译:通过实验装置的设计,通过原位电化学测量和失重测量研究了碳钢在H_2S / CO_2环境动态高压下的电化学腐蚀行为。还进行了计算流体动力学(CFD),以模拟样品表面的流速和切应力。结果表明,阳极和阴极过程均受活化控制。阻抗谱的特征是双电容半圆。原位电化学测量符合样品表面流速和剪切应力的CFD模拟。

著录项

  • 来源
    《Corrosion science》 |2012年第12期|p.37-47|共11页
  • 作者单位

    School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Hubei Key Laboratory of Materials Chemistry and Service Failure, Wuhan 430074, China;

    School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Hubei Key Laboratory of Materials Chemistry and Service Failure, Wuhan 430074, China;

    School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Hubei Key Laboratory of Materials Chemistry and Service Failure, Wuhan 430074, China;

    Southwest Branch of China Petroleum Engineering Co., Ltd., Chengdu, Sichuan 610017, China;

    Southwest Branch of China Petroleum Engineering Co., Ltd., Chengdu, Sichuan 610017, China;

    School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Hubei Key Laboratory of Materials Chemistry and Service Failure, Wuhan 430074, China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    A. Steel; B. SEM; B. EIS; C. Acid corrosion;

    机译:A.钢;扫描电镜B.EIS;C.酸腐蚀;

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