Electrochemically-induced TiO_2 incorporation for enhancing corrosion and tribocorrosion resistance of PEO coating on 7075 Al alloy

摘要

7075 Al alloy wasPEO-treated in a silicate based electrolyte containing 3 g l(-1) potassium titanyl oxalate using unipolar and bipolar pulsed current waveforms. The coating formed by the bipolar waveform with the wider cathodic pulses showed volcano-like surface morphology with no evidence of large pores at the metal/coating interface. It revealed the highest corrosion performance due to the synergistic effect of TiO2 incorporation and structural/morphological features along with a better passivation behavior indicating no pitting susceptibility. For this coating, the tribocorrosion tests showed no potential drop during sliding under 1 N with the lowest volume loss of 0.022 mm(3).