Catalytic asymmetric oxidations using optically active (salen)manganese (Ⅲ) complexes as catalysts

Tsutomu Katsuki

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Catalytic asymmetric oxidations using optically active (salen)manganese (Ⅲ) complexes as catalysts

机译：旋光性（锰）锰（Ⅲ）配合物作为催化剂的催化不对称氧化

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This review deals with enantioselective one oxygen atom transfer reactions (epoxidation, oxidation of enolates, and oxidation of sulphide to sulphoxides) catlaysed by optically active (salen)manganese(Ⅲ)complexes. Asymmetric aziridination is also discussed briefly.

机译：本文综述了由光学活性的（锰）锰（Ⅲ）络合物催化的对映选择性的一个氧原子转移反应（环氧化，烯醇化物的氧化以及硫化物向亚砜的氧化）。还简要讨论了不对称的叠氮化。

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来源
《Coordination chemistry reviews》 |1995年第1995期|p.189-214|共26页
作者
Tsutomu Katsuki;
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作者单位

Department of Chemistry, Faculty of Science, Kyushu University 33, Hakozaki, Higashi-ku, Fukuoka 812, Japan;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
oxidation; catalysis; (salen)manganese(Ⅲ); optical activity;

机译：氧化;催化;（硒）锰（Ⅲ）;光学活性;

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专利

1. Synthesis of resins with pendently-bound chiral manganese-salen complexes and use as heterogeneous asymmetric alkene epoxidation catalysts [J] . L. Canali, D.C. Sherringto, H. Deleuze Reactive & Functional Polymers . 1999,第2期

机译：侧键性手性锰-salen配合物的树脂合成及其用作多相不对称烯烃环氧化催化剂
2. Comparative Study of Aerobic Alkene Epoxidations Catalyzed by Optically Active Manganese(III) and Cobalt(II) Salen Complexes [J] . O.A. Kholdeeva, M.P. Vanina Reaction kinetics & catalysis letters . 2001,第1期

机译：光学活性锰（III）和钴（II）Salen配合物催化好氧烯烃环氧化的比较研究
3. A comparative study of the asymmetric epoxidation of aromatic olefins using the first generation manganese salen epoxidation catalysts and their light fluorous variants: an interesting discovery on the use of benzotrifluoride as a cosolvent [J] . Yuki Kobayashi, Sae Inukai, Naoki Asai, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2014,第16a17期

机译：使用第一代锰salen环氧化催化剂及其轻质氟代化合物对芳族烯烃不对称环氧化的比较研究：关于使用苯并三氟化物作为助溶剂的有趣发现
4. Chiral (Salen) Complexes Encapsulated in Mesoporous ZSM-5 as an Optical Active Catalyst for Aymmetric Phenolic Ring Opening of Terminal Epoxides [C] . Kwang-Yeon Lee, Young-Hee Lee, Chang-Kyo Shin, IUMRS International Conference in Asia . 2007

机译：在中孔ZSM-5中包封的手性（盐）复合物作为末端环氧化物的非对称酚类环开口的光学活性催化剂
5. Development and mechanistic studies of a highly active and selective oligomeric (Salen)cobalt(III) catalyst for asymmetric epoxide ring-opening reactions [D] . White, David Emery 2006

机译：用于不对称环氧化物开环反应的高活性和选择性低聚（Salen）钴（III）催化剂的开发和机理研究
6. Oligomeric (Salen)Mn(III) Complexes Featuring Tartrate Linkers Immobilized over Layered Double Hydroxide for Catalytically Asymmetric Epoxidation of Unfunctionalized Olefins [O] . Yihong Jia, Asma A. ALOthman, Rui Liang, 2020

机译：寡聚（Salen）Mn（III）配合物其具有固定在层状双氢氧化物上的酒石酸酯的连接剂用于催化不官能化烯烃的不对称环氧化
7. Asymmetric Reactions Using Optically Active (Salen)ruthenium Complexes as Catalysts [O] . Tsutomu KATSUKI 2000

机译：使用光学活性（Salen）钌配合物作为催化剂的不对称反应
8. Sterically controlled syntheses of optically active organic compounds. 13: Catalytic hydrogenation of symmetric substrates in the presence of asymmetric molecules [R] . Yoshida, T. 1971

机译：空间控制的光学活性有机化合物的合成。图13：在不对称分子存在下对称底物的催化氢化

Catalytic asymmetric oxidations using optically active (salen)manganese (Ⅲ) complexes as catalysts

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