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Preparation and characterization of foamed concrete with Ti-extracted residues and red gypsum

机译:钛渣和红石膏泡沫混凝土的制备与表征

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The recycling of Ti-extracted residues (TRs) and red gypsum (RG), which are the industrial wastes from titanium dioxide manufacturing industry, will avoid the increasing impact on the environment due to their difficulty for disposal. In this paper, the ternary blended binder mainly consisting of ordinary Portland cement (OPC), TRs and RG for the preparation of foamed concrete (FC) was formulated in the laboratory. The hydration kinetics of blended cement, mechanical characteristics and microstructure of FC were investigated. The results indicated that quick lime and sulfoaluminate cement (SAC) evidently reduced the setting time of the complex binder, but mechanical activation for TRs could not substantially shorten those of blended binder. In the case of FC, the optimum technological parameters were proposed as follows: OPC: TRs: RG = 10:45:45 (by mass, the same below), quick lime 2%, SAC 4%, Na2SO4 0.4%, water reducer 0.2%, foam 4.6% and WEB 0.60. The maximum compressive strength and specific strength of FC with density of 437 kg/m(3) reached up to 2.14 MPa and 4.91 kN center dot m/kg, respectively. Microstructure analysis revealed that the interconnected assemblages in FC are fioccular and petal-like hydrated gels, need-like ettringite and unreactive plate-like gypsum. (C) 2018 Elsevier Ltd. All rights reserved.
机译:钛提取残留物(TRs)和红石膏(RG)的回收是二氧化钛制造业的工业废物,由于其难以处置,将避免对环境造成越来越大的影响。本文在实验室中配制了主要由普通硅酸盐水泥(OPC),TRs和RG组成的三元共混粘合剂,用于制备泡沫混凝土(FC)。研究了水泥混合料的水化动力学,FC的力学性能和微观结构。结果表明,生石灰和硫铝酸盐水泥(SAC)明显减少了复合粘合剂的凝结时间,但TR的机械活化不能显着缩短混合粘合剂的凝结时间。对于FC,建议的最佳工艺参数如下:OPC:TRs:RG = 10:45:45(按质量计,下同),生石灰2%,SAC 4%,Na2SO4 0.4%,减水剂0.2%,泡沫4.6%和WEB 0.60。 FC的最大抗压强度和密度为437 kg / m(3)的比强度分别达到2.14 MPa和4.91 kN中心点m / kg。微观结构分析表明,FC中的相互连接的组合是球状和花瓣状的水合凝胶,需要的钙矾石和不活泼的板状石膏。 (C)2018 Elsevier Ltd.保留所有权利。

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