Fabrication and properties of 3-3 type PZT-ordinary Portland cement composites

摘要

In this study, porous lead zirconate titanate (PZT) ceramics with porosity ranging from 46.4% to 82.3% were produced by the gel casting technology of particle-stabilized ceramic foams with the solid loading of 5-25 vol%, then the Portland cement paste was cast in porous PZT ceramics with continuous vibration to fabricate 3-3 type cement-based piezoelectric composites. The microstructure, dielectric, piezoelectric, and electromechanical coupling properties of the composites were characterized. With the increase in initial solid loading of PZT slurry, both the porosity, open porosity and pore size of porous PZT ceramics decreased correspondingly, which have prevented the filling of cement paste into the porous ceramics and led to the increment of PZT content in the composites. Increase in the PZT content contributed to the relative permittivity (epsilon(r)) and longitudinal piezoelectric strain coefficient (d(33)), and a resultant reduction in piezoelectric voltage coefficient (g(33)). The prepared composites possessed a maximal thickness electromechanical coupling coefficient (K-t) value of 41.22%, higher than that of planar electromechanical coupling coefficient (K-p), indicating enhanced thickness mode oscillations of the composite. With the increase in PZT volume fraction, the PZT-cement composites turned from typical 3-3 structure to appoximate sandwich structure gradually, leading to more energy loss during electromechanical process and obvious decrease of the mechanical quality factor (Q(m)). The acoustic impedance (Z) of specimens ranged from 6.69 to 8.27 MRayls, close to that of cement materials (similar to 10 MRayls), making them promising candidate for application in civil engineering.