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High flexural strength and durability of concrete reinforced by in situ polymerization of acrylic acid and 1-acrylanmido-2-methylpropanesulfonic acid

机译:丙烯酸和1-丙烯酰胺-2-甲基丙磺酸原位聚合加固混凝土高弯曲强度及耐久性

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摘要

Brittleness of the normal concrete has an adverse effect on its application in structures undertaking the bending load. In the current study, concrete was modified by in situ polymerization of acrylic acid (AA) and 1-acrylanmido-2-methylpropanesulfonic acid (AMPS) during cement hydration to strengthen their flexural strength and durability. By adding 7 wt% of AA-AMPS to the concrete, the flexural strength of concrete showed an increment of 61.2% in comparison to the reference one, which was attributed to the polymerization reaction of AA-AMPS monomers that took place at the early stage of the cement hydration, and the rapid formation of polymer network could also densify and compact the interfacial transition zone (ITZ) in the cement matrix. The water and chloride resistances were also enhanced with the increased amount of AA-AMPS. In conclusion, this strategy has great potential to develop high perfor-mance concrete with enhanced flexural properties and durability. (c) 2021 Elsevier Ltd. All rights reserved.
机译:正常混凝土的脆性对其在弯曲载荷的结构中的应用具有不利影响。在目前的研究中,通过在水泥水合过程中以丙烯酸(AA)和1-丙烯酰胺-2-甲基丙二磺酸(AMPS)的原位聚合来改性混凝土,以加强其抗弯强度和耐久性。通过将7wt%的AA-AMPS加入混凝土中,与参考文献相比,混凝土的抗弯强度显示为61.2%,其归因于在早期发生的AA-AMPS单体的聚合反应水泥水合作用,聚合物网络的快速形成也可以在水泥基质中致密化和紧凑的界面过渡区(ITZ)。随着AA-AMP的增加,还增强了水和氯化物电阻。总之,该策略具有巨大的潜力,可利用增强的弯曲性能和耐用性开发出高性造型的混凝土。 (c)2021 elestvier有限公司保留所有权利。

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  • 来源
    《Construction and Building Materials》 |2021年第19期|123428.1-123428.9|共9页
  • 作者单位

    Univ Macau Inst Appl Phys & Mat Engn Joint Key Lab Minist Educ Ave Univ Taipa Macau Peoples R China;

    Southeast Univ Sch Mat Sci & Engn Nanjing 211189 Peoples R China;

    Univ Macau Inst Appl Phys & Mat Engn Joint Key Lab Minist Educ Ave Univ Taipa Macau Peoples R China;

    Univ Macau Inst Appl Phys & Mat Engn Joint Key Lab Minist Educ Ave Univ Taipa Macau Peoples R China;

    Univ Macau Inst Appl Phys & Mat Engn Joint Key Lab Minist Educ Ave Univ Taipa Macau Peoples R China;

    Univ Macau Inst Appl Phys & Mat Engn Joint Key Lab Minist Educ Ave Univ Taipa Macau Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Concrete; In situ polymerization; Flexural strength; Interfacial transition zone; Durability;

    机译:混凝土;在原位聚合;弯曲强度;界面过渡带;耐久性;

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