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Effect of CFBC ash as partial replacement of PCC ash in alkali-activated material

机译:CFBC灰作为碱活化材料中PCC灰的部分替代品的作用

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The present study investigates the effect of partial replacement of conventional pulverized coal combustion (PCC) fly ash with circulating fluidized bed combustion (CFBC) ash in alkali activated material. The alkali activated material was produced by using sodium hydroxide (4M, 5M and 6M) and sodium silicate solution. The characteristics of alkali activated materials were assessed by evaluating compressive strength, along with microstructure and physiochemical properties. A strong correlation was observed between the mole concentration of sodium hydroxide and compressive strength of alkali activated materials containing CFBC ash. The microstructural and physiochemical results revealed that the calcium rich CFBC ash significantly affects the formation of polymerization products. A hybrid form of polymerization product was formed which resulted in densified microstructure. Furthermore, higher molarity of sodium hydroxide can unlock the polymerization potential of CFBC ash. The findings also revealed that incorporation of lower amount of CFBC ash is an efficient way to reduce the formation of sulfoaluminates in alkali activated materials incorporating CFBC ash. (C) 2020 Elsevier Ltd. All rights reserved.
机译:本研究调查了碱性活化材料中循环流化床燃烧(CFBC)灰部分替代常规粉煤燃烧(PCC)飞灰的效果。通过使用氢氧化钠(4M,5M和6M)和硅酸钠溶液生产碱活化材料。通过评估抗压强度以及微观结构和理化性质来评估碱活化材料的特性。观察到氢氧化钠的摩尔浓度与含CFBC灰的碱活化材料的抗压强度之间存在很强的相关性。微观结构和物理化学结果表明,富含钙的CFBC灰分显着影响聚合产物的形成。形成了混合形式的聚合产物,其导致致密的微观结构。此外,较高摩尔浓度的氢氧化钠可释放CFBC灰的聚合潜能。研究结果还表明,掺入少量CFBC灰是减少掺入CFBC灰的碱活化材料中硫铝酸盐形成的有效方法。 (C)2020 Elsevier Ltd.保留所有权利。

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