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The effects of calcium stearate on mechanical and durability aspects of self-consolidating concretes incorporating silica fumeatural zeolite

机译:硬脂酸钙对掺入硅粉/天然沸石的自固结混凝土的机械和耐久性方面的影响

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Moisture and aggressive ions transfer into concrete can be considered a significant threat to the durability of self-consolidating concretes (SCCs). To restrict moisture and aggressive ions transfer into concrete, utilizing damp-proofing agents is expected to be beneficial. These admixtures can decrease permeability of concrete, especially the permeability under non-hydrostatic condition, by providing a water-repellent layer along the capillary pores. This study investigated the impacts of calcium stearate (CS), as a damp proofing agent, on durability properties of SCCs which were prepared with various types of supplementary cementitious materials (SCMs). In addition to durability properties, the effects of CS on mechanical characteristics and properties of fresh concrete, and microstructure have been studied as well. The outcomes demonstrated that in fresh concrete, CS (up to 7 kg/m(3)) prompted a decrease in workability and density of fresh concrete without any significant impact on slump loss. The results of hardened concrete evaluation also showed a reduction in either density of hardened concrete or compressive strength. Plus, microstructure analysis showed that incorporation of CS deteriorates both the cement paste and the interfacial transient zone. Eventually, although CS had a negligible impact on electrical resistivity, total water absorption, and chloride diffusivity, it was absolutely effective on permeability of concrete under non-hydro static pressure. In this regard, inclusion of CS drastically reduced the depth of capillary penetration of water in addition to short and long term water absorption. As a case in point, incorporation of 7 kg/m(3) of CS decreased the last-mentioned parameters by respectively 60%, 72%, and 40% compared to the reference mixture after 120 days of moist curing. (C) 2019 Elsevier Ltd. All rights reserved.
机译:水分和侵蚀性离子转移到混凝土中可以认为是对自凝结混凝土(SCC)耐久性的重大威胁。为了限制水分和侵蚀性离子转移到混凝土中,预期使用防潮剂将是有益的。这些掺合料可通过沿毛细孔提供疏水层来降低混凝土的渗透性,特别是在非静水条件下的渗透性。这项研究调查了硬脂酸钙(CS)作为防潮剂对用各种类型的辅助胶凝材料(SCM)制备的SCC耐久性的影响。除耐久性能外,还研究了CS对新鲜混凝土的机械特性和性能以及微观结构的影响。结果表明,在新鲜混凝土中,CS(高达7 kg / m(3))促使新鲜混凝土的可加工性和密度降低,而对坍落度损失没有任何重大影响。硬化混凝土评估的结果还显示硬化混凝土的密度或抗压强度均降低。另外,微结构分析表明,CS的掺入会破坏水泥浆和界面过渡带。最终,尽管CS对电阻率,总吸水率和氯离子扩散率的影响可忽略不计,但对非水静压下的混凝土渗透性绝对有效。在这方面,除了短期和长期吸水之外,CS的加入还大大降低了水的毛细渗透深度。举例来说,在湿固化120天后,与参考混合物相比,加入7 kg / m(3)的CS可使后述参数分别降低60%,72%和40%。 (C)2019 Elsevier Ltd.保留所有权利。

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