Reaction mechanisms of calcined kaolin processing waste-based geopolymers in the presence of low alkali activator solution

摘要

The massive amount of kaolin processing waste was daily formed. To reduce the amount of their waste deposited in landfills and to increase the value- adding of recyclable waste, this work interested to use as raw materials in the preparation of geopolymer. This paper studied the reaction mechanisms of calcined kaolin processing waste-based geopolymers in the presence of low alkali activator solution by the pressing method. The reaction mechanisms of geopolymer were measured as a function of NaOH concentration by DSC, XRD, and FTIR analysis. Furthermore, the effects of NaOH concentration and curing time on the mechanical properties and microstructure of calcined kaolin processing waste-based geopolymer were investigated. The DSC, XRD, and FTIR results indicated that the geopolymerization reaction increased with higher NaOH concentrations. Forming the geopolymer by the pressing method led to the particles being close together in a compact matrix. Subsequently, their surfaces were dissolved with NaOH solution, inducing the geopolymerization reaction. This reaction and continuous reaction resulted in the compressive strength and microstructure of the geopolymer. The compressive strengths of the geopolymer synthesized with NaOH concentration of 10 M (curing time of 7 days) and a curing time of 28 days were 26.98 MPa and 28.55 MPa, respectively, which were approximately 22.58% and 52.35% higher compared to the geopolymer synthesized with NaOH concentration of 4 M and a curing time of 1 day. The SEM micrographs of the geopolymer samples displayed more geopolymeric gel and denser matrices with increases in NaOH concentration and curing time. The nitrogen adsorption and pore volume decreased with increases in NaOH concentration and curing time. Synthesis of geopolymers using kaolin processing waste as a raw material is a value- adding and environmentally friendly process. (C) 2019 Elsevier Ltd. All rights reserved.